You actually seem to have a pretty good deal working already. You understand that SQL is powerful, but like any powerful tool it requires some basic knowledge of the tool and/or instruction before you can use it safely. You've got somebody managing your SQL Server that understands your limits and is providing you with stored procedures to do the "heavy lifting" on the SQL side. This is definitely not a bad place to start!
I'm not sure what kind of resources you are looking for (web sites, classes, books, etc). I'll give you a couple of my suggestions, but feel free to ask more or different questions.
First and foremost, asking questions here is likely to be a really good source of information for you. There are a bunch of crusty old pharts like me, and a few folks that actually present a professional image too. We all have opinions, and most of those opinions are pretty good, and lord knows if you ask a question you're pretty likely to get some good answers.
Don't overlook the possibility of classes at a local university, trade school, or even an Adult Education class. The hands on nature and the interaction with people is really valuable to most people in the early stages of the learning process for almost anything. The quality varies all over the map, running from astounding (in a good sense) to astounding (as in a waste of time) depending on the class, instructor, and student... While this can definitely be a "mixed bag" and can go wrong, it usually goes very, VERY right.
If you are looking for books, then I'd recommend
SQL Queries for Mere Mortals or the
Hitchhiker's Guide for someone using Microsoft SQL Server.
There are literally thousands of other resources. Give me a nudge in the right direction and I bet I can suggest something!
-PatP