We run postgresql and mysql on the same server for our virtual hosting customers, doesn't seem to cause any problems, but then I wouldn't expect it to do so if things are kept balanced out, as long as the number of DBs and users and usage are kept as sensible levels then you won't have any more problems running both than you would just running one. The only downfall I can see is that you may have your server optimised for mySQL which may make it less optimum for pgSQL - but if you're only developing the system then it's not a problem, but if you plan to run two live systems then it is something to consider.
Thanks,