I remember having problems when using this kind of setup.
I remember solving them by having all the stations pointing theyr NET dir (the BDE NET dir) on the mapped drive, which has to be exactly the same drive (say N

and has to contain a dir which in turn would contain the NET file.
Also keep much more short the DATA alias path, and remember NOT to use UNC names, but ALWAYS mapped drives; the BDE is known to have all sorts of strange problems with UNC names.