2) Sorry if I have to say that, but you do have differences in your system configuration (hardware/software) and/or DB2 configuration and data. The DB2 optimizer works deterministic, so you would get the same results in the same environment and data. You should investigate why you believe that there are no differences, find the differences and figure out if they may result in different access plans. If you can't find any difference, search again...
3) Are those physical devices real physical discs or just partitions on the same disc? If you have multiple discs, it makes sense to have multiple containers on the file system because you can benefit from parallel I/O at the DB2 level (not only at OS level).
That also depends on how your physical volume is organized. For example, if the volume already stripes over physical volumes and you have mostly sequential access, then multiple containers may not give you much advantage because you already have multi-page reads (due to prefetching), and the OS uses parallel I/O.