Having moved data from from z/OS to DB2 on Linux, I can speak from some experience. Both z/OS and iSeries are EBCDIC and AIX is ASCII. The best way to do this is to set up a DB2 connection from a Windows or AIX box to the "host" database on iSeries. This will require that you set up a Type 2 connection with the following statements:
- catalog tcpip node
- catalog dcs database (this is an extra step required to connect to z/OS or iSeries host)
- catalog database
Then using the db2 command line in AIX, do a regular export of the tables:
db2 "export to employee.ixf of ixf select * from employee"
Then load or import the data onto DB2 for AIX using the export file created.
See if you can find someone in the company who has set up a type 2 connection from Windows to the iSeries database, and this will help you with doing the connection. Note that you will need a license for DB2 Connect to do this, but if you have DB2 ESE Version 8 (and I think V9, but not V9.5) it comes with a free license for DB2 Connect that allows you to connect to a iSeries or z/OS database.
You could do the export on Windows DB2 Command Line and then transfer it to AIX when you are done for the DB2 load/import.