This is the format for adding a nullable column:
alter table schemaname.tablename add column columnname integer;
This is true for DB2 on all platforms. By adding WITH DEFAULT, you are giving the column a default value: an empty string for CHAR columns, 0 for numeric columns, current date or time or timestamp for date/time columns, etc.. The default value will be used instead of null if a row is inserted without providing a value for the column.