First, check what's wrong with C:\DB2\NODE0000\SQL00002\SQLT0003.0 (does it exist?) and if you can recover this db using a backup image from some other db2 environment (prod/test).
You need to read about db2move, db2look, tablespaces, etc... in the manual. db2move exports all tables (in all tablespaces) by default. Exported data will be in IXF format (contains definition - DDL - for most objects). You can find some examples in the manual or on the web. Here is the link to v9.5 Info Center:
IBM DB2 9.5 Information Center for Linux, UNIX, and Windows