It seems you should read documentation more carefully

From documentation:
Many computer systems and some disk-drive manufacturers keep information for a physical disk drive on the drive itself. This information is sometimes referred to as a volume table of contents (VTOC) or disk label. The VTOC is commonly stored on the first track of the drive. A table of alternate sectors and bad-sector mappings (also called a revectoring table) might also be stored on the first track.
If you plan to allocate partitions at the start of a disk, you might need to use offsets to prevent the database server from overwriting critical information required by the operating system. For the exact offset required, refer to your disk-drive manuals
In other words, the offset allows you to define more than one dbspace or
chunk on the same device such that no two chunks overlap.
Check out the documentation...there are a lot of information about using offset when creating/adding chunks.