Howdy. Let's assume that your list is in $D$4:$E$9. Then in $G$4:$G9 put the numbers: 1-6
In cell H4, put this formula:
=LARGE($E$4:$E$9,$G4)
Copy down to row 9.
Then in I4 put this formula:
INDEX($D$4:$E$9,MATCH(H4,$E$4:$E9,),1)
Copy down to row 9.
If you use the relative and absolute references correctly, you can extend each list with little effort.