The limit on Excel files is that two or more can't make changes at the same time, unless shared, and then the last one in makes the changes. But in your case, there are many trying to access the same Excel files, rather that the db is accessing the files sequentially. That shouldn't be a problem.
Do you have the Excel files on your computer? If so, then it may think that it is trying to access at the same time (I occasionally have had a problem with copying XL files to a network).