Not sure I understand fully, but if you have the Form in Access, it is most likely based on a query.
In Excel, go to Data > PivotTable, then select "External data" and in the resulting dialog box, choose MS Access, then OK, then navigate to the query underlying the Form. Go through the appropriate dialog boxes, and then finally import the data.
After that data is set, you can select Layout and position the items wherever you desire (drag and drop). Once you click OK, then you can go to each field and select by dropdown list what you want to see.
HTH