Welcome to the Board!
Are you trying to prevent duplicate entries? If so, this may be of interest:
http://support.microsoft.com/default...&Product=xlw2K
If duplicates are ok, but you just want them highlighted, select your data range and Goto Format-->Conditional Formatting-->Formula Is-->=COUNTIF($A$1:$A$33,A1)>1 Then select the Patterns Tab-->Red.
Where A1:A33 represents your range of data.
Hope that helps,
Smitty