Something like this should work out:
Code:
select case when unicode(substring (ntextcolumn, 1, 1)) < 255 then 'English'
when unicode(substring (ntextcolumn, 1, 1)) < 3000 then 'Hindi' end
from yourtable
Like I said before, you will need to adjust the values and order of checks to make sure you get the right results. You will also need to make sure you get the first non-whitespace character.