Off the top of my head I can see two potential solutions here:
1. A batch process that runs every minute that identifies the new entries and sends out the emails.
2. The insert statement is being executed by some process into the table. If this is in
VB then have this process send out the email.
As I said previously it is not possible to execute
VB code inside a trigger so alternatives is all we can go with. I have used both above on other projects and these appear to work fine.