Thank you for your reply. I probably would want it to reside on the TSQL server in the form of a trigger.
The end goal would be that when a record is indexed (inserted) into a TSQL table, in this case purchase_order, using the TSQL column po_number, query the PSQL purchase_order table by the po_number value that was just inserted into the TSQL column, grab other PSQL column values so those values could be then updated in the TSQL purchase_order table.
I'm probably not explaining very well, but basically a database lookup to update values in a purchase order based on a key field. The idea is to only have a person have to manually enter in the purchase order number in an application with a TSQL 2008 database and have the rest of that data, which resides in a PSQL 2011 database, to auto populate. It is a canned application with no programming interface.
Again, thank you.