To set the field seperator to a newline, use FS="". That said, if you want to use awk just to print a particular line, do it like this...
df -k | awk 'NR==1{print; exit}'
The use of 'exit' isn't really necessary but for larger files, you proabably wouldn't want to continue reading in lines.
You could also use 'head' in this instance...
df -k | head -1
Damian