I solved this one on my own. Probably far from the most elegant, but this is what I did:
For i = 1 to Rec_count
For j = i to Rec_count
if CaldTime( i ) <> "" and CaldTime( j ) <> "" then
if( DateDiff("s",DateValue(CaldTime( i )) &" "& (FormatDateTime(CaldTime(i ),4)), DateValue(CaldTime( j)) &" "& (FormatDateTime(CaldTime(j ),4))) > 0) then
temp = CaldTime(j)
CaldTime( j ) = CaldTime( i )
CaldTime( i ) = temp
End If
End If
Next
Next